SURFACE MECHANISM FOR AMMONIA DECOMPOSITION OVER NICKEL
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****     N2/H2/NH3 - SURFACE MECHANISM OVER NI                        *
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****     References:S. Appari, V.M. Janardhanan, S. Jayanti, L. Maier,* 
****     S. Tischer, O. Deutschmann, Chem., Eng. Sci. 66 (2011)       *
****     5184-5191                                                    *
****     Contact: mail@detchem.com (O. Deutschmann)                   * 
****     www.detchem.com/mechanisms                                   * 
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****     Kinetic data:                                                *
****      k = A * T**b * exp (-Ea/RT)         A          b       Ea   *
****                                       (cm,mol,s)    -     kJ/mol *
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****     STICK: A in next reaction is initial sticking coefficient    *
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****     (DETCHEM format)                                             *
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STICK
H2      +NI(s)   +NI(s)   >H(s)    +H(s)      1.000E-02    0.0      0.00
H(s)    +H(s)    >NI(s)   +NI(s)   +H2        3.315E+19    0.0     82.21
****
STICK
O2      +NI(s)   +NI(s)   >O(s)    +O(s)      1.000E-02    0.0      0.00
O(s)    +O(s)    >NI(s)   +NI(s)   +O2        3.928E+23    0.0    473.41
****
STICK
H2O     +NI(s)   >H2O(s)                      1.000E-01    0.0      0.00
H2O(s)  >NI(s)   +H2O                         4.747E+12    0.0     62.09
****
O(s)    +H(s)    >OH(s)   +NI(s)              5.000E+22    0.0     97.90
OH(s)   +NI(s)   >O(s)    +H(s)               1.761E+21    0.0     36.00
****
OH(s)   +H(s)    >H2O(s)  +NI(s)              3.000E+20    0.0     42.70
H2O(s)  +NI(s)   >OH(s)   +H(s)               2.068E+21    0.0     91.07
****
OH(s)   +OH(s)   >O(s)    +H2O(s)             3.000E+21    0.0    100.00
O(s)    +H2O(s)  >OH(s)   +OH(s)              5.871E+23    0.0    210.27
****
STICK
NH3     +NI(s)   >NH3(s)                      1.100E-02    0.0      0.00
NH3(s)  >NI(s)   +NH3                         8.210E+14    0.0     78.63
****
STICK
N2      +NI(s)   +NI(s)   >N(s)    +N(s)      1.000E-06    0.0      0.00
N(s)    +N(s)    >NI(s)   +NI(s)   +N2        4.442E+22    0.0    210.84
****
NH3(s)  +NI(s)   >NH2(s)  +H(s)               5.723E+22    0.0     78.99
NH2(s)  +H(s)    >NH3(s)  +NI(s)              1.320E+24    0.0     48.81
****
NH2(s)  +NI(s)   >NH(s)   +H(s)               2.718E+22    0.0     75.74
NH(s)   +H(s)    >NH2(s)  +NI(s)              3.702E+19    0.0     74.87
****
NH(s)   +NI(s)   >N(s)    +H(s)               6.213E+19    0.0     22.93
N(s)    +H(s)    >NH(s)   +NI(s)              2.070E+19    0.0    156.04
****
END