!SURFACE MECHANISM FOR OXIDATION OF CO OVER PLATINUM
!***********************************************************************
!****                                                                  *
!****     CO/O2 OVER PT - SURFACE MECHANISM                            *
!****     thermodynamically consistent (273 - 1273K)                   *
!****                                                                  *
!****     D. CHAN, O. DEUTSCHMANN                                      *
!****     KIT (Karlsruhe Institute of Technology)                      *
!****                                                                  *
!****     References:                                                  *
!****     D. Chan, S. Tischer, J. Heck, C. Diehm, O. Deutschmann       *
!****     Applied Catalysis B: Environmental 156–157 (2014) 153–165    *
!****     www.detchem.com/mechanisms                                   * 
!****     KIT (Karlsruhe Institute of Technology)                      *
!****     Contact: mail@detchem.com (O. Deutschmann)                   * 
!****     www.detchem.com/mechanisms                                   * 
!****                                                                  *
!****                                                                  *
!****     Kinetic data:                                                *
!****      k = A * T**b * exp (-Ea/RT)         A          b       Ea   *
!****                                       (cm,mol,s)    -     kJ/mol *
!****                                                                  *
!****     STICK: A in next reaction is initial sticking coefficient    *
!****                                                                  *
!****                                                                  *
!****     (CHEMKIN format)                                             *
!****                                                                  * 
!***********************************************************************
REACTIONS  KJOULES/MOLE  MWOFF 
O2 + (Pt) => O2(Pt)                           5.000E-02  0.000      0.000 
    STICK 
O2(Pt) => (Pt) + O2                           5.243E+11  -0.069     19.573 
O2(Pt) + (Pt) => O(Pt) + O(Pt)                8.325E+13  -0.000     39.933 
O(Pt) + O(Pt) => O2(Pt) + (Pt)                4.444E+21  0.000      264.067 
    COV / O(Pt)                               0.000E+00  0.000      -88.200 / 
CO + (Pt) => CO(Pt)                           8.400E-01  0.000      0.000 
    STICK 
CO(Pt) => (Pt) + CO                           7.635E+12  -0.139     143.145 
    COV / CO(Pt)                              0.000E+00  0.000      -29.300 / 
CO2 + (Pt) => CO2(Pt)                         3.193E-03  -0.035     2.686 
    STICK 
CO2(Pt) => (Pt) + CO2                         1.894E+10  0.139      21.855 
CO(Pt) + O2(Pt) => CO2(Pt) + O(Pt)            4.124E+13  0.069      9.494 
    COV / O(Pt)                               0.000E+00  0.000      44.100 / 
CO2(Pt) + O(Pt) => CO(Pt) + O2(Pt)            2.910E+23  -0.069     272.506 
    COV / CO(Pt)                              0.000E+00  0.000      29.300 / 
CO(Pt) + O(Pt) => CO2(Pt) + (Pt)              4.764E+13  0.069      101.361 
    COV / CO(Pt)                              0.000E+00  0.000      -29.300 / 
CO2(Pt) + (Pt) => CO(Pt) + O(Pt)              6.297E+20  -0.069     140.239 
    COV / O(Pt)                               0.000E+00  0.000      44.100 / 
END