!SURFACE MECHANISM FOR STEAM REFORMING AND PARTIAL OXIDATION 
!OF METHANE AND HEXADECANE OVER RHODIUM
!***********************************************************************
!****                                                                  *
!****     SR/CPO CH4/C16H34 ON RH - SURFACE MECHANISM                  *
!****                                                                  *
!****     Version 1.0, March  2008                                     *
!****     L. Maier, O. Deutschmann                                     *
!****     KIT (Karlsruhe Institute of Technology)                      *
!****     Contact: mail@detchem.com (O. Deutschmann)                   * 
!****                                                                  *
!****     References:                                                  *
!****     J. Thormann, L. Maier, P. Pfeifer, U. Kunz, K. Schubert,     *
!****     O. Deutschmann.International J. Hydrogen Energy              *
!****     34 (2009), 5108-5120                                         * 
!****     www.detchem.com/mechanisms                                   * 
!****                                                                  *
!****     Kinetic data:                                                *
!****      k = A * T**b * exp (-Ea/RT)         A          b       Ea   *
!****                                       (cm,mol,s)    -     kJ/mol *
!****                                                                  *
!****     STICK: A in next reaction is initial sticking coefficient    *
!****                                                                  *
!****                                                                  *
!****     (SURFACE CHEMKIN format)                                     *
!****                                                                  * 
!***********************************************************************      
SITE/RH_SURFACE/    SDEN/2.72E-9/
_Rh_ H2O_Rh H_Rh OH_Rh CO_Rh C_Rh CH3_Rh CH2_Rh 
CH_Rh CH4_Rh O_Rh CO2_Rh
HCO_Rh 
END
REACTIONS  JOULES/MOLE  MWOFF 
H2 + _Rh_ + _Rh_ => H_Rh + H_Rh 0.01 0. 0. 
    STICK 
H_Rh + H_Rh => _Rh_ + _Rh_ + H2 3.E+21 0. 77800. 
O2 + _Rh_ + _Rh_ => O_Rh + O_Rh 0.01 0. 0. 
    STICK 
O_Rh + O_Rh => _Rh_ + _Rh_ + O2 1.3E+22 0. 355200. 
CH4 + _Rh_ => CH4_Rh 0.008 0. 0. 
    STICK 
CH4_Rh => _Rh_ + CH4 2.E+14 0. 25100. 
H2O + _Rh_ => H2O_Rh 0.1 0. 0. 
    STICK 
H2O_Rh => _Rh_ + H2O 6.E+13 0. 45000. 
CO2 + _Rh_ => CO2_Rh 0.00001 0. 0. 
    STICK 
CO2_Rh => _Rh_ + CO2 3.E+8 0. 21700. 
CO + _Rh_ => CO_Rh 0.5 0. 0. 
    STICK 
CO_Rh => _Rh_ + CO 1.E+13 0. 133400. 
    COV / CO_Rh 0. 0. -50000. / 
O_Rh + H_Rh => OH_Rh + _Rh_ 5.E+22 0. 83700. 
OH_Rh + _Rh_ => O_Rh + H_Rh 3.E+20 0. 37700. 
OH_Rh + H_Rh => H2O_Rh + _Rh_ 3.E+20 0. 33500. 
H2O_Rh + _Rh_ => OH_Rh + H_Rh 5.E+22 0. 106400. 
OH_Rh + OH_Rh => O_Rh + H2O_Rh 3.E+21 0. 100800. 
O_Rh + H2O_Rh => OH_Rh + OH_Rh 3.E+21 0. 171800. 
O_Rh + C_Rh => CO_Rh + _Rh_ 5.E+23 0. 97900. 
CO_Rh + _Rh_ => O_Rh + C_Rh 3.7E+21 0. 169000. 
    COV / CO_Rh 0. 0. -50000. / 
O_Rh + CO_Rh => CO2_Rh + _Rh_ 1.E+19 0. 121600. 
    COV / CO_Rh 0. 0. -50000. / 
CO2_Rh + _Rh_ => O_Rh + CO_Rh 5.E+21 0. 115300. 
CO_Rh + H_Rh => HCO_Rh + _Rh_ 5.E+19 0. 108900. 
HCO_Rh + _Rh_ => CO_Rh + H_Rh 3.7E+21 0. 0. 
    COV / CO_Rh 0. 0. 50000. / 
HCO_Rh + _Rh_ => O_Rh + CH_Rh 8.E+23 0. 59500. 
O_Rh + CH_Rh => HCO_Rh + _Rh_ 3.7E+21 0. 167500. 
CH4_Rh + _Rh_ => CH3_Rh + H_Rh 5.5E+20 0. 61000. 
CH3_Rh + H_Rh => CH4_Rh + _Rh_ 3.7E+21 0. 51000. 
CH3_Rh + _Rh_ => CH2_Rh + H_Rh 3.7E+24 0. 103000. 
CH2_Rh + H_Rh => CH3_Rh + _Rh_ 3.7E+21 0. 44000. 
CH2_Rh + _Rh_ => CH_Rh + H_Rh 3.7E+24 0. 100000. 
CH_Rh + H_Rh => CH2_Rh + _Rh_ 3.7E+24 0. 68000. 
CH_Rh + _Rh_ => C_Rh + H_Rh 3.7E+21 0. 21000. 
C_Rh + H_Rh => CH_Rh + _Rh_ 3.7E+21 0. 172800. 
O_Rh + CH4_Rh => CH3_Rh + OH_Rh 1.7E+24 0. 80340. 
CH3_Rh + OH_Rh => O_Rh + CH4_Rh 3.7E+21 0. 24270. 
O_Rh + CH3_Rh => CH2_Rh + OH_Rh 3.7E+24 0. 120310. 
CH2_Rh + OH_Rh => O_Rh + CH3_Rh 3.7E+21 0. 15060. 
O_Rh + CH2_Rh => CH_Rh + OH_Rh 3.7E+24 0. 114500. 
CH_Rh + OH_Rh => O_Rh + CH2_Rh 3.7E+21 0. 36820. 
O_Rh + CH_Rh => C_Rh + OH_Rh 3.7E+21 0. 30130. 
C_Rh + OH_Rh => O_Rh + CH_Rh 3.7E+21 0. 136000. 
CO_Rh + H_Rh => C_Rh + OH_Rh 3.7E+21 0. 142760. 
C_Rh + OH_Rh => CO_Rh + H_Rh 3.7E+20 0. 25540. 
C16H34 + 16 _Rh_ => 2 CH3_Rh + 14 CH2_Rh 422807.09 0.2 71000. 
    FORD/ C16H34 0.495 / 
    FORD/ _Rh_ 0.9 / 
END