!MECHANISM OF GASPHASE REACTION IN CVD OF CARBON FROM C2H2,C2H4,C3H6 !**** !********************************************************************* !**** * !**** GAPHASE MECHANISM FOR CHEMICAL VAPOR DEPOSITION OF * !**** CARBON FROM LIGHT HYDROCARBONS (C2H2, C2H4, C3H6). * !**** * !**** Version 1.0, March 2005 * !**** * !**** K. Norinaga, O. Deutschmann * !**** Karlsruhe University, Germany * !**** * !**** NOTE: That is a first version that needs further * !**** improvements, * !**** * !**** CHEMKIN format * !**** * !**** Reference: * !**** K. Norinaga and O. Deutschmann * !**** Detailed gasphase chemistry in CVD of carbon from * !**** unsaturated light hydrocarbons * !**** Proc. EUROCVD-15, Bochum, September 4-9, 2005 * !**** * !**** Kinetic data: * !**** k = A * T**b * exp (-Ea/RT) A b Ea * !**** (cm,mol,s) - kJ/mol * !**** * !**** see manuals on www.detchem.com for details * !**** * !**** The kinetic data of the backward reactions are calculated * !**** from thermodynamics (k_b = k_f /K) * !**** * !**** Notes: Reactions after " **** times (value) " * !**** are adjusted from their originally reported values. * !**** "A" is multiplied by a factor of a value indicated. * !**** * !********************************************************************* ELEMENTS C H END SPECIES 1-C6H12 1CH2 3CH2 4m1pent A1C2H A1C2H)2 A1C2H* A1C2H- A1C2H3 A1C2H3* A1C2H5 A2 A2-1 A2-2 A2C2H)2 A2C2H-1 A2C2H-1* A2C2H-2 A2C2H-2* A2C2H-23 A2C2H2-1 A2C2H2-2 A2C2H3-2 A2C2H5 A2C6H4-1 A2C6H4-2 A2C6H5-2 A2CH2-1 A2CH2-2 A2CH3-1 A2CH3-2 A2R5 A2R5-1 A2R5-3 A2R5-4 A2R5-5 A2R5E-1 A2R5E-3 A2R5E-4 A2R5E-5 A2R5E12 A2R5E34 A2R5E43 A2R5E45 A2R5E54 A2R5H2 A2T1 A2T2 A3 A3-1 A3-2 A3-4 A3-9 A3C2H-1 A3C2H-1* A3C2H-2 A3C2H-2* A3C2H-4 A3C2H2-4 A3CH2 A3CH2R A3CH3 A3L A3L-1 A3L-2 A3L-9 A3LE-1 A3LE-1P A3LE-2 A3LE-2P A3LE-2S A3LR5 A3LR5* A3R5 A3R5-10* A3R5-7* A4 A4-1 A4-2 A4-4 A4C2H-1 A4C2H-1* A4C2H-2 A4C2H-2* A4C2H-4 A4C2H-4* A4L A4L* AC3H4 AC3H5 ACH3CH2 ACH3CH3 ANTHAN BAA3L BAA3L-1 BAA3L-12 BAA3L-4 BAPYR BAPYR* BBFLTHN BBFLTHN* BENZNAP BENZNAP* BENZYLB BENZYLB* BEPYR BEPYR* BGHIF BGHIF- BGHIPE BGHIPE* BIPHEN BIPHENH BKFLTHN C C-C6H12 C-C6H4 C-C6H7 C10H10 C10H9 C17H12 C2 C2H C2H2 C2H3 C2H4 C2H5 C2H6 C3H2 C3H3 C3H6 C3H8 C4H C4H2 C4H4 C4H512 C4H52 C4H6 C4H61 C4H612 C4H62 C4H8 C5H2 C5H3 C5H4 C5H4H C5H5 C5H6 C5H7 C5H8 C6H C6H2 C6H3 C6H4CH3 C6H5 C6H6 C6H8 C6H813 C6H814 C7H7 C7H8 C8H2 C9H7 C9H8 CH CH3 CH4 COR COR- COR1 COR1- COR2 COR2- COR3 COR3- COR4 COR4- CORONEN CPBFL CPBFL* CPBPER CPCDA4 CPCDA4* CPCDFL CPCDFL* CRYSN CRYSN-1 CRYSN-4 CRYSN-5 CYC3H4 DCPA4 FLTHN FLTHN-1 FLTHN-3 FLTHN-7 H H2 HA2R5 HB I-A1C2H2 I-C3H7 I-C4H3 I-C4H5 I-C4H51 I-C4H7 I-C6H5 I-C6H7 INA4 L-C5H3 L-C5H4 L-C5H5 L-C5H7 L-C5H8 L-C6H4 L-C6H6 N-A1C2H2 N-C3H7 N-C4H3 N-C4H5 N-C4H51 N-C6H5 N-C6H7 P2 P2- PC3H4 PERYLN PERYLN* SC3H5 TC3H5 fluorene END REACTIONS KJOULES/MOLE H + H +M <=> H2 +M 1.000E+18 -1.000 0.000 H2 / 0. / CH4 / 2. / C2H6 / 3. / H2 + H + H <=> H2 + H2 9.200E+16 -0.600 0.000 H + CH <=> H2 + C 1.100E+14 0.000 0.000 H2 + CH <=> H + 3CH2 1.107E+08 1.790 6.990 H2 + CH <=> CH3 3.190E+25 -4.990 11.340 CH + 3CH2 <=> C2H3 3.090E+14 -1.980 2.590 H + 3CH2 (+M) <=> CH3 (+M) 2.500E+22 -0.800 0.000 LOW / 3.200E+21 -3.140 5.150 / TROE / 0.68 78. 1995. 5590. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H2 + 3CH2 <=> H + CH3 5.000E+05 2.000 30.250 C + 3CH2 <=> H + C2H 5.000E+13 0.000 0.000 CH + 3CH2 <=> H + C2H2 4.000E+13 0.000 0.000 CH + 3CH2 <=> H + H + C2H 5.490E+22 -2.410 48.200 3CH2 + 3CH2 <=> H + C2H3 7.120E+21 -3.900 10.290 3CH2 + 3CH2 <=> C2H4 1.110E+20 -3.430 8.660 3CH2 + 3CH2 <=> H2 + C2H2 3.200E+13 0.000 0.000 H + 1CH2 <=> H2 + CH 3.000E+13 0.000 0.000 H + 1CH2 <=> H + 3CH2 2.000E+14 0.000 0.000 H2 + 1CH2 <=> H + CH3 7.000E+13 0.000 0.000 1CH2 + 1CH2 <=> H2 + C2H2 3.010E+13 0.000 0.000 1CH2 + 1CH2 <=> H + C2H3 2.000E+13 0.000 0.000 H + CH3 (+M) <=> CH4 (+M) 1.270E+22 -0.630 1.600 LOW / 2.477E+27 -4.760 10.210 / TROE / 0.783 74. 2941. 6964. / H2 / 2. / CH4 / 2. / C2H6 / 3. / CH3 + C <=> H + C2H2 5.000E+13 0.000 0.000 CH3 + CH <=> H + C2H3 3.000E+13 0.000 0.000 CH3 + 3CH2 <=> H + C2H4 4.000E+13 0.000 0.000 CH3 + 3CH2 <=> C2H5 2.530E+20 -3.490 8.490 CH3 + 1CH2 <=> H + C2H4 1.200E+13 0.000 -2.380 CH3 + 1CH2 <=> C2H5 1.111E+19 -3.200 7.450 CH3 + CH3 (+M) <=> C2H6 (+M) 2.120E+22 -0.970 2.590 LOW / 1.770E+44 -9.670 26.030 / TROE / 0.5325 151. 1038. 4970. / H2 / 2. / CH4 / 2. / C2H6 / 3. / CH3 + CH3 <=> H2 + C2H4 1.000E+16 0.000 134.020 CH3 + CH3 <=> H + C2H5 4.990E+12 0.100 44.350 H + CH4 <=> H2 + CH3 6.600E+08 1.620 45.360 CH4 + CH <=> H + C2H4 6.000E+13 0.000 0.000 CH4 + 3CH2 <=> CH3 + CH3 2.460E+06 2.000 34.600 CH4 + 1CH2 <=> CH3 + CH3 1.600E+13 0.000 -2.380 H2 + C2 <=> H + C2H 4.000E+05 2.400 4.180 C2H +M <=> H + C2 +M 4.680E+16 0.000 518.840 H2 / 0. / CH4 / 2. / C2H6 / 3. / H + C2H (+M) <=> C2H2 (+M) 1.000E+23 -1.000 0.000 LOW / 3.750E+27 -4.800 7.950 / TROE / 0.6464 132. 1315. 5566. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H2 + C2H <=> H + C2H2 4.900E+05 2.500 2.340 C2H + 1CH2 <=> CH + C2H2 1.810E+13 0.000 0.000 C2H + 3CH2 <=> CH + C2H2 1.810E+13 0.000 0.000 CH3 + C2H <=> H + C3H3 2.410E+13 0.000 0.000 CH3 + C2H <=> PC3H4 8.070E+49 -11.305 183.270 CH4 + C2H <=> CH3 + C2H2 1.810E+12 0.000 2.090 C2H + C2H <=> C4H2 1.800E+13 0.000 0.000 C2H + C2H <=> C2H2 + C2 1.810E+12 0.000 0.000 C2H5 + C2H <=> C2H4 + C2H2 1.810E+12 0.000 0.000 H + C2H2 (+M) <=> C2H3 (+M) 5.600E+18 0.000 10.040 LOW / 3.800E+34 -7.270 30.210 / TROE / 0.7507 98.5 1302. 4167. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + C2H2 <=> CH + 1CH2 5.490E+22 -2.410 48.200 H2 + C2H2 <=> C2H4 1.410E+41 -9.060 213.940 CH + C2H2 <=> H + C3H2 3.000E+13 0.000 0.000 C2H2 + 3CH2 <=> H + C3H3 1.200E+13 0.000 27.700 C2H2 + 1CH2 <=> H + C3H3 2.000E+13 0.000 0.000 C2H2 + 1CH2 <=> C2H2 + 3CH2 4.000E+13 0.000 0.000 C2H2 + 1CH2 <=> CYC3H4 1.660E+38 -8.650 25.480 C2H2 + 1CH2 <=> AC3H4 7.460E+39 -8.780 26.570 C2H2 + 1CH2 <=> PC3H4 2.620E+40 -8.860 26.820 CH3 + C2H2 <=> H + AC3H4 2.870E+21 -2.740 103.770 CH3 + C2H2 <=> PC3H4 + H 1.000E+13 -0.530 56.070 CH3 + C2H2 <=> AC3H5 1.400E+04 2.210 69.040 C2H2 + C2H <=> H + C4H2 9.600E+13 0.000 0.000 C2H2 + C2H <=> N-C4H3 1.300E+30 -6.120 10.500 C2H2 + C2H <=> I-C4H3 1.600E+34 -7.280 20.210 C2H2 + C2H2 <=> H2 + C4H2 1.500E+13 0.000 178.670 C2H2 + C2H2 <=> C4H4 5.500E+12 0.000 154.650 H + C2H3 (+M) <=> C2H4 (+M) 6.080E+18 0.270 1.170 LOW / 1.400E+24 -3.860 13.890 / TROE / 0.782 207.5 2663. 6095. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + C2H3 <=> H2 + C2H2 3.000E+13 0.000 0.000 CH + C2H3 <=> C2H2 + 3CH2 5.000E+13 0.000 0.000 C2H3 + 1CH2 <=> CH3 + C2H2 1.810E+13 0.000 0.000 C2H3 + 3CH2 <=> CH3 + C2H2 1.810E+13 0.000 0.000 C2H3 + 3CH2 <=> H + AC3H4 3.000E+13 0.000 0.000 CH3 + C2H3 <=> H + AC3H5 7.200E+13 0.000 0.000 CH3 + C2H3 <=> CH4 + C2H2 3.920E+11 0.000 0.000 C2H3 + C2H <=> C2H2 + C2H2 3.000E+13 0.000 0.000 C2H3 + C2H <=> C4H4 2.120E+60 -13.450 115.270 C2H3 + C2H2 <=> H + C4H4 4.600E+16 -1.250 35.150 C2H3 + C2H2 <=> N-C4H5 2.400E+31 -6.950 23.430 C2H3 + C2H2 <=> I-C4H5 1.000E+37 -8.770 41.010 C2H3 + C2H3 <=> C2H4 + C2H2 1.440E+13 0.000 0.000 C2H3 + C2H3 <=> C4H6 1.500E+52 -11.970 67.370 C2H3 + C2H3 <=> I-C4H5 + H 7.200E+28 -4.490 59.830 C2H3 + C2H3 <=> N-C4H5 + H 4.600E+24 -3.380 61.510 C2H3 + C2H3 <=> H + H + C4H4 7.830E+12 0.000 0.000 C2H4 (+M) <=> H2 + C2H2 (+M) 8.000E+18 0.440 371.430 LOW / 7.000E+44 -9.310 417.830 / TROE / 0.7345 180. 1035. 5417. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + C2H4 (+M) <=> C2H5 (+M) 1.080E+18 0.454 7.620 LOW / 1.200E+36 -7.620 29.160 / TROE / 0.9753 210. 987. 4374. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + C2H4 <=> H2 + C2H3 1.330E+06 2.530 51.210 CH + C2H4 <=> H + AC3H4 1.750E+15 -0.380 0.420 CH + C2H4 <=> AC3H5 1.670E+34 -7.600 15.440 C2H4 + 1CH2 <=> C3H6 9.030E+13 0.000 0.000 C2H4 + 3CH2 <=> H + AC3H5 3.190E+12 0.000 22.110 CH3 + C2H4 <=> CH4 + C2H3 2.270E+05 2.000 38.490 C2H4 + C2H <=> H + C4H4 1.200E+13 0.000 0.000 C2H4 + C2H3 <=> H + C4H6 7.400E+14 -0.660 35.230 C2H4 + C2H3 <=> I-C4H7 2.110E+22 -4.700 4.980 C2H4 + C2H4 <=> C2H5 + C2H3 5.010E+14 0.000 270.720 H + C2H5 (+M) <=> C2H6 (+M) 5.210E+23 -0.990 6.610 LOW / 1.990E+35 -7.080 27.970 / TROE / 0.8422 125. 2219. 6882. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + C2H5 <=> H2 + C2H4 2.000E+12 0.000 0.000 C2H5 + 1CH2 <=> CH3 + C2H4 9.030E+12 0.000 0.000 C2H5 + 1CH2 <=> H + C3H6 9.030E+12 0.000 0.000 C2H5 + 3CH2 <=> CH3 + C2H4 1.810E+13 0.000 0.000 CH3 + C2H5 <=> CH4 + C2H4 1.950E+13 -0.500 0.000 CH3 + C2H5 <=> C3H8 3.370E+13 0.000 0.000 C2H5 + C2H <=> CH3 + C3H3 1.810E+13 0.000 0.000 C2H5 + C2H2 <=> C2H6 + C2H 2.710E+11 0.000 98.100 C2H5 + C2H3 <=> C2H6 + C2H2 4.820E+11 0.000 0.000 C2H5 + C2H5 <=> C2H6 + C2H4 1.390E+12 0.000 0.000 H + C2H6 <=> H2 + C2H5 1.150E+08 1.900 31.510 C2H6 + 1CH2 <=> CH3 + C2H5 4.000E+13 0.000 -2.300 CH3 + C2H6 <=> CH4 + C2H5 6.140E+06 1.740 43.720 C2H6 + C2H3 <=> C2H5 + C2H4 1.500E+13 0.000 41.800 CH + C3H2 <=> H + C4H2 5.000E+13 0.000 0.000 C3H2 + 3CH2 <=> N-C4H3 + H 5.000E+13 0.000 0.000 CH3 + C3H2 <=> H + C4H4 5.000E+12 0.000 0.000 C3H2 + C3H2 <=> C4H2 + C2H2 2.000E+13 0.000 355.660 C3H2 + C3H2 <=> H2 + C6H2 2.000E+13 0.000 355.660 C3H3 <=> H + C3H2 5.200E+12 0.000 328.240 H + C3H3 (+M) <=> AC3H4 (+M) 3.000E+19 0.000 0.000 LOW / 1.400E+25 -5.000 -25.110 / TROE / 0.5 2000. 10. 10000. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + C3H3 (+M) <=> PC3H4 (+M) 3.000E+19 0.000 0.000 LOW / 1.400E+25 -5.000 -25.110 / TROE / 0.5 2000. 10. 10000. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + C3H3 <=> H2 + C3H2 5.000E+13 0.000 4.180 CH + C3H3 <=> N-C4H3 + H 7.000E+13 0.000 0.000 CH + C3H3 <=> I-C4H3 + H 5.000E+13 0.000 0.000 C3H3 + 3CH2 <=> H + C4H4 2.000E+13 0.000 0.000 CH3 + C3H3 (+M) <=> C4H612 (+M) 1.500E+19 0.000 0.000 LOW / 2.600E+52 -11.940 40.880 / TROE / 0.175 1340. 60000. 9769. / H2 / 2. / CH4 / 2. / C2H6 / 3. / C3H3 + C2H3 <=> H + C5H5 9.630E+40 -7.800 120.590 C3H3 + C3H3 <=> C6H6 3.000E+12 0.000 0.000 AC3H4 <=> PC3H4 2.500E+12 0.000 246.870 H + AC3H4 <=> H2 + C3H3 1.150E+08 1.900 31.510 CH3 + AC3H4 <=> CH4 + C3H3 1.000E+12 0.000 33.470 C2H + AC3H4 <=> C3H3 + C2H2 1.000E+13 0.000 0.000 C3H3 + AC3H4 <=> H + C6H6 1.400E+12 0.000 41.840 PC3H4 + H <=> H2 + C3H3 1.150E+08 1.900 31.510 PC3H4 + H <=> TC3H5 4.000E+12 0.000 8.790 PC3H4 + CH3 <=> CH4 + C3H3 1.000E+12 0.000 33.470 PC3H4 + C2H <=> C3H3 + C2H2 1.000E+13 0.000 0.000 CYC3H4 <=> AC3H4 1.510E+14 0.000 210.880 CYC3H4 <=> PC3H4 7.080E+13 0.000 182.850 AC3H5 <=> H + AC3H4 1.790E+13 0.840 250.000 H + AC3H5 <=> H2 + AC3H4 1.000E+13 0.000 0.000 AC3H5 + 1CH2 <=> H + C4H6 3.010E+13 0.000 0.000 CH3 + AC3H5 <=> CH4 + AC3H4 4.860E+11 -0.320 0.550 C2H + AC3H5 <=> C3H3 + C2H3 2.000E+01 0.000 0.000 C2H + AC3H5 <=> C2H2 + AC3H4 1.500E-01 0.000 0.000 C2H + AC3H5 <=> C5H6 4.820E+13 0.000 0.000 C2H2 + AC3H5 <=> L-C5H7 3.190E+10 0.000 29.100 C2H3 + AC3H5 <=> C2H4 + AC3H4 2.410E+12 0.000 0.000 C2H3 + AC3H5 <=> C3H6 + C2H2 4.820E+12 0.000 0.000 C2H3 + AC3H5 <=> H + H + C5H6 1.590E+65 -14.000 256.340 C2H4 + AC3H5 <=> H + C5H8 6.030E+09 0.000 48.060 C2H5 + AC3H5 <=> C2H6 + AC3H4 9.640E+11 0.000 -0.550 C2H5 + AC3H5 <=> C3H6 + C2H4 2.590E+12 0.000 -0.550 AC3H5 + AC3H5 <=> C3H6 + AC3H4 8.430E+10 0.000 -1.100 SC3H5 <=> CH3 + C2H2 1.300E+13 0.000 139.750 C3H6 <=> CH3 + C2H3 2.500E+14 0.000 368.210 C3H6 <=> H + AC3H5 2.900E+13 0.000 334.740 C3H6 <=> CH4 + C2H2 3.500E+12 0.000 292.700 C3H6 <=> PC3H4 + H2 2.000E+13 0.000 334.740 H + C3H6 <=> CH3 + C2H4 3.400E+13 0.000 14.640 H + C3H6 <=> H2 + AC3H5 6.000E+12 0.000 6.280 H + C3H6 <=> TC3H5 + H2 1.300E+15 0.000 95.400 H + C3H6 <=> SC3H5 + H2 2.500E+15 0.000 95.400 C3H6 + 1CH2 <=> CH3 + AC3H5 7.230E+11 0.000 25.910 CH3 + C3H6 <=> CH4 + AC3H5 2.210E+00 3.500 23.750 CH3 + C3H6 <=> TC3H5 + CH4 1.100E+11 0.000 46.440 CH3 + C3H6 <=> SC3H5 + CH4 2.100E+11 0.000 46.440 C3H6 + C2H <=> PC3H4 + C2H3 1.210E+13 0.000 0.000 C3H6 + C2H <=> CH + C4H61 1.210E+13 0.000 0.000 C3H6 + C2H3 <=> C2H4 + AC3H5 1.000E+12 0.000 33.470 C3H6 + C2H3 <=> CH3 + C4H6 7.230E+11 0.000 20.960 C3H6 + C2H5 <=> C2H6 + AC3H5 2.230E+00 3.500 27.770 C3H6 + C3H3 <=> AC3H5 + AC3H4 1.000E+12 0.000 33.470 C3H6 + C3H6 <=> I-C3H7 + AC3H5 2.530E+14 0.000 231.000 C3H6 + C3H6 <=> N-C3H7 + AC3H5 4.880E+13 0.000 219.000 C3H6 + C3H6 <=> 1-C6H12 1.940E+08 2.500 154.000 C3H6 + C3H6 <=> 4m1pent 2.650E+08 2.100 150.000 N-C3H7 <=> H + C3H6 1.260E+13 0.000 161.000 N-C3H7 <=> CH3 + C2H4 1.210E+13 0.000 126.000 N-C3H7 + H <=> H2 + C3H6 1.810E+12 0.000 0.000 N-C3H7 + 3CH2 <=> C2H5 + C2H4 1.810E+13 0.000 0.000 N-C3H7 + 3CH2 <=> CH3 + C3H6 1.810E+12 0.000 0.000 N-C3H7 + CH3 <=> CH4 + C3H6 1.850E+12 -0.320 0.000 N-C3H7 + C2H <=> C3H6 + C2H2 6.030E+12 0.000 0.000 N-C3H7 + C2H <=> C3H3 + C2H5 1.210E+13 0.000 0.000 N-C3H7 + C2H3 <=> C3H6 + C2H4 1.210E+12 0.000 0.000 N-C3H7 + C2H3 <=> C3H8 + C2H2 1.210E+12 0.000 0.000 N-C3H7 + C2H5 <=> C3H8 + C2H4 1.150E+12 0.000 0.000 N-C3H7 + C2H5 <=> C3H6 + C2H6 1.450E+12 0.000 0.000 N-C3H7 + C2H6 <=> C3H8 + C2H5 2.530E-01 3.820 37.830 N-C3H7 + AC3H5 <=> C3H8 + AC3H4 7.230E+11 0.000 -0.550 N-C3H7 + C3H6 <=> C3H8 + AC3H5 2.230E+00 3.500 27.770 N-C3H7 + N-C3H7 <=> C3H8 + C3H6 1.690E+12 0.000 0.000 N-C3H7 + C3H8 <=> I-C3H7 + C3H8 8.440E-04 4.000 19.770 I-C3H7 <=> CH3 + C2H4 1.000E+12 0.000 145.000 I-C3H7 <=> H + C3H6 1.600E+13 0.000 150.000 I-C3H7 + H <=> H2 + C3H6 3.610E+12 0.000 0.000 I-C3H7 + H <=> C3H8 2.000E+13 0.000 0.000 I-C3H7 + CH3 <=> CH4 + C3H6 4.530E+12 0.680 0.000 I-C3H7 + C2H <=> C3H6 + C2H2 3.610E+12 0.000 0.000 I-C3H7 + C2H2 <=> CH3 + C4H6 2.770E+10 0.000 27.210 I-C3H7 + C2H3 <=> C3H6 + C2H4 2.820E+12 -0.700 0.000 I-C3H7 + C2H3 <=> C3H8 + C2H2 1.520E+14 -0.700 0.000 I-C3H7 + C2H5 <=> C3H6 + C2H6 2.300E+13 -0.350 0.000 I-C3H7 + C2H5 <=> C3H8 + C2H4 1.840E+13 -0.350 0.000 I-C3H7 + C2H6 <=> C3H8 + C2H5 8.440E-01 4.200 36.470 I-C3H7 + AC3H5 <=> C3H8 + AC3H4 4.580E+12 -0.350 -0.550 I-C3H7 + C3H6 <=> C3H8 + AC3H5 6.620E-02 4.000 33.770 N-C3H7 + I-C3H7 <=> C3H8 + C3H6 5.130E+13 -0.350 0.000 I-C3H7 + I-C3H7 <=> C3H8 + C3H6 2.110E+14 -0.700 0.000 H + C3H8 <=> N-C3H7 + H2 1.330E+06 2.540 28.270 H + C3H8 <=> I-C3H7 + H2 1.300E+06 2.400 18.710 CH3 + C3H8 <=> N-C3H7 + CH4 9.040E-01 3.650 29.930 CH3 + C3H8 <=> I-C3H7 + CH4 1.510E+00 3.460 22.930 H + C4H (+M) <=> C4H2 (+M) 1.000E+23 -1.000 0.000 LOW / 3.750E+27 -4.800 7.950 / TROE / 0.6464 132. 1315. 5566. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H2 + C4H <=> H + C4H2 4.900E+05 2.500 2.340 C4H + C2H2 <=> H + C6H2 9.600E+13 0.000 0.000 H + C4H2 <=> N-C4H3 3.300E+50 -11.800 62.800 H + C4H2 <=> I-C4H3 2.600E+46 -10.150 64.860 CH + C4H2 <=> H + C5H2 5.000E+13 0.000 0.000 C4H2 + 3CH2 <=> L-C5H3 + H 1.300E+13 0.000 0.000 C4H2 + 1CH2 <=> L-C5H3 + H 3.000E+13 0.000 0.000 C4H2 + C2H <=> C4H + C2H2 2.000E+13 0.000 0.000 C4H2 + C2H <=> H + C6H2 9.600E+13 0.000 0.000 C4H2 + C2H <=> C6H3 1.300E+30 -6.120 10.500 C4H2 + C4H <=> H + C8H2 1.200E+14 0.000 0.000 C4H2 + C4H2 <=> H + H + C8H2 1.510E+14 0.000 234.320 C4H2 + C4H2 <=> H2 + C8H2 1.510E+13 0.000 178.670 N-C4H3 <=> I-C4H3 1.000E+51 -12.450 213.390 N-C4H3 + H <=> I-C4H3 + H 9.200E+11 0.630 12.510 N-C4H3 + H <=> C2H2 + C2H2 1.300E+20 -1.850 12.390 N-C4H3 + H <=> C4H4 1.100E+42 -9.650 29.290 N-C4H3 + H <=> H2 + C4H2 1.500E+13 0.000 0.000 N-C4H3 + C2H2 <=> L-C6H4 + H 1.800E+19 -1.950 55.230 N-C4H3 + C2H2 <=> N-C6H5 4.100E+33 -7.120 57.320 N-C4H3 + C2H2 <=> C6H5 9.800E+68 -17.580 110.880 N-C4H3 + C2H2 <=> H + C-C6H4 3.500E+41 -8.630 96.240 N-C4H3 + C2H3 <=> H + C6H5 6.000E+12 0.000 0.000 N-C4H3 + C4H2 <=> A1C2H- 9.800E+68 -17.580 110.880 N-C4H3 + C4H2 <=> A1C2H* 3.330E+24 -3.890 38.540 I-C4H3 + H <=> C2H2 + C2H2 3.700E+22 -2.500 21.510 I-C4H3 + H <=> C4H4 5.300E+46 -10.680 38.790 I-C4H3 + H <=> H2 + C4H2 3.000E+13 0.000 0.000 I-C4H3 + H2 <=> C2H3 + C2H2 5.010E+10 0.000 83.680 I-C4H3 + 3CH2 <=> C2H + AC3H4 2.000E+13 0.000 0.000 I-C4H3 + C2H3 <=> H + C6H5 6.000E+12 0.000 0.000 C4H4 <=> H2 + C4H2 1.260E+15 0.000 396.240 H + C4H4 <=> N-C4H5 1.100E+50 -11.940 56.070 H + C4H4 <=> I-C4H5 2.100E+52 -12.440 64.860 H + C4H4 <=> N-C4H3 + H2 6.650E+05 2.530 51.210 H + C4H4 <=> I-C4H3 + H2 3.330E+05 2.530 38.660 C4H4 + C2H <=> I-C4H3 + C2H2 4.000E+13 0.000 0.000 C4H4 + C2H <=> N-C4H3 + C2H2 4.000E+13 0.000 0.000 C4H4 + C2H <=> C4H2 + C2H3 1.000E+13 0.000 0.000 C4H4 + C2H2 <=> H + C6H5 1.000E+09 0.000 126.000 C4H4 + C2H2 <=> C6H6 4.470E+11 0.000 126.000 C4H4 + C2H3 <=> L-C6H6 + H 1.900E+17 -1.320 44.350 C4H4 + C2H3 <=> N-C4H3 + C2H4 5.000E+11 0.000 68.200 C4H4 + C2H3 <=> I-C4H3 + C2H4 5.000E+11 0.000 68.200 C4H4 + C4H4 <=> A1C2H3 7.500E+13 0.000 159.000 N-C4H5 <=> I-C4H5 4.900E+66 -17.260 231.800 N-C4H5 + H <=> I-C4H5 + H 1.000E+34 -5.610 77.410 N-C4H5 + H <=> H2 + C4H4 1.500E+13 0.000 0.000 N-C4H5 + C2H2 <=> N-C6H7 1.100E+14 -1.270 12.130 N-C4H5 + C2H2 <=> C-C6H7 5.000E+24 -5.460 19.250 N-C4H5 + C2H2 <=> L-C6H6 + H 5.800E+08 1.020 45.610 N-C4H5 + C2H2 <=> H + C6H6 2.100E+15 -1.070 20.080 N-C4H5 + C2H3 <=> H2 + C6H6 2.800E-07 5.630 -7.910 N-C4H5 + C2H3 <=> C6H813 5.500E+15 -1.670 6.150 N-C4H5 + AC3H4 <=> H + C7H8 2.000E+11 0.000 15.480 PC3H4 + N-C4H5 <=> H + C7H8 3.160E+11 0.000 15.480 N-C4H5 + C4H2 <=> H + A1C2H 3.160E+11 0.000 7.530 N-C4H5 + C4H4 <=> H + A1C2H3 3.160E+11 0.000 2.510 I-C4H5 + H <=> H2 + C4H4 3.000E+13 0.000 0.000 I-C4H5 + H <=> CH3 + C3H3 2.000E+13 0.000 8.370 C4H52 <=> H + C4H4 3.000E+13 0.000 188.290 C4H52 + C3H3 <=> H + C7H7 3.000E+12 0.000 0.000 C4H52 + C4H52 <=> H + ACH3CH2 3.000E+12 0.000 0.000 C4H512 <=> H + C4H4 3.000E+13 0.000 188.290 N-C4H51 <=> H + C4H4 3.000E+13 0.000 188.290 N-C4H51 <=> C2H4 + C2H 2.000E+14 0.000 238.500 I-C4H51 <=> H + C4H4 3.000E+13 0.000 188.290 I-C4H51 + C3H3 <=> H + C7H7 3.000E+12 0.000 0.000 I-C4H51 + I-C4H51 <=> H + ACH3CH2 3.000E+12 0.000 0.000 C4H6 <=> I-C4H5 + H 3.300E+45 -8.950 484.950 C4H6 <=> N-C4H5 + H 8.500E+54 -11.780 533.490 C4H6 <=> C2H4 + C2H2 6.400E+13 0.000 322.600 C4H6 <=> H2 + C4H4 2.520E+15 0.000 396.240 H + C4H6 <=> N-C4H5 + H2 1.330E+06 2.530 51.210 H + C4H6 <=> I-C4H5 + H2 6.650E+05 2.530 38.660 CH3 + C4H6 <=> N-C4H5 + CH4 4.000E+14 0.000 95.400 CH3 + C4H6 <=> I-C4H5 + CH4 2.000E+14 0.000 95.400 C4H6 + C2H2 <=> C6H814 2.300E+12 0.000 146.450 C4H6 + C2H3 <=> N-C4H5 + C2H4 5.000E+14 0.000 95.400 C4H6 + C3H3 <=> N-C4H5 + AC3H4 1.000E+13 0.000 94.140 C4H6 + C3H3 <=> I-C4H5 + AC3H4 1.000E+13 0.000 94.140 C4H612 <=> C4H6 2.500E+13 0.000 263.600 C4H612 <=> CH3 + C3H3 2.000E+15 0.000 313.810 H + C4H612 <=> CH3 + AC3H4 6.000E+12 0.000 8.790 H + C4H612 <=> PC3H4 + CH3 6.000E+12 0.000 8.790 H + C4H612 <=> H2 + C4H512 6.500E+13 0.000 39.330 H + C4H612 <=> H + C4H6 2.000E+13 0.000 16.740 H + C4H612 <=> I-C4H5 + H2 1.700E+05 2.500 10.420 CH3 + C4H612 <=> CH4 + C4H512 1.000E+14 0.000 81.590 C4H612 + C2H3 <=> C4H512 + C2H4 7.500E+12 0.000 41.840 C4H612 + C3H3 <=> C4H512 + AC3H4 5.000E+12 0.000 81.590 C4H61 <=> CH3 + C3H3 3.000E+15 0.000 317.160 C4H61 <=> C4H612 2.500E+13 0.000 271.970 H + C4H61 <=> CH3 + AC3H4 1.300E+05 2.500 4.180 H + C4H61 <=> C2H5 + C2H2 6.500E+04 2.500 4.180 H + C4H61 <=> I-C4H51 + H2 6.500E+13 0.000 39.330 H + C4H61 <=> N-C4H51 + H2 6.500E+13 0.000 39.330 CH3 + C4H61 <=> I-C4H51 + CH4 1.000E+14 0.000 81.590 CH3 + C4H61 <=> N-C4H51 + CH4 1.000E+14 0.000 81.590 C4H61 + C2H3 <=> N-C4H51 + C2H4 1.500E+13 0.000 41.800 C4H61 + C3H3 <=> N-C4H51 + AC3H4 1.000E+13 0.000 81.590 C4H62 <=> C4H6 3.000E+13 0.000 271.970 C4H62 <=> C4H612 3.000E+13 0.000 280.340 C4H62 <=> H + C4H52 5.000E+14 0.000 365.280 H + C4H62 <=> PC3H4 + CH3 2.600E+05 2.500 4.180 CH3 + C4H62 <=> CH4 + C4H52 2.000E+14 0.000 81.590 C4H62 + C2H3 <=> C4H52 + C2H4 1.500E+13 0.000 41.800 C4H62 + C3H3 <=> C4H52 + AC3H4 1.000E+13 0.000 81.590 I-C4H7 <=> H + C4H6 3.160E+13 0.000 145.610 I-C4H7 + H <=> H2 + C4H6 1.820E+12 0.000 0.000 I-C4H7 + H <=> C4H8 1.000E+14 0.000 0.000 C4H8 <=> CH3 + AC3H5 1.100E+16 0.000 325.080 H + C5H3 <=> C5H4 1.000E+14 0.000 0.000 C5H4 <=> L-C5H4 1.000E+13 0.000 25.110 H + C5H4 <=> H2 + C5H3 1.000E+06 2.500 20.920 L-C5H5 + H <=> L-C5H4 + H2 1.810E+12 0.000 0.000 L-C5H5 + CH3 <=> L-C5H4 + CH4 1.950E+13 -0.500 0.000 C5H5 <=> C3H3 + C2H2 2.790E+79 -18.300 547.440 C5H5 <=> L-C5H5 1.640E+96 -23.500 574.950 C5H5 <=> C5H4H 5.170E+80 -20.400 402.460 H + C5H5 <=> C5H6 2.000E+14 0.000 0.000 H + C5H5 <=> H2 + C5H4 3.230E+07 2.095 66.290 CH3 + C5H5 <=> CH4 + C5H4 2.000E+12 0.000 63.010 CH3 + C5H5 <=> H + C-C6H7 2.440E+41 -7.989 164.270 C5H5 + AC3H5 <=> C5H6 + AC3H4 1.000E+12 0.000 0.000 C5H5 + C5H5 <=> H + H + A2 5.000E+12 0.000 33.470 C5H4H <=> C3H3 + C2H2 3.400E+80 -19.200 427.900 H + C5H4H <=> H2 + C5H4 2.800E+13 0.000 9.450 H + C5H6 <=> H2 + C5H5 2.190E+08 1.770 12.550 H + C5H6 <=> H2 + C5H4H 2.800E+13 0.000 147.030 H + C5H6 <=> C2H2 + AC3H5 6.600E+14 0.000 51.650 CH3 + C5H6 <=> CH4 + C5H5 3.110E+11 0.000 23.010 CH3 + C5H6 <=> CH4 + C5H4H 1.800E-01 4.000 137.580 C5H6 + C2H3 <=> C5H5 + C2H4 6.000E+12 0.000 0.000 C5H6 + AC3H5 <=> C5H5 + C3H6 2.000E-01 4.000 0.000 N-C4H5 + C5H6 <=> C5H5 + C4H6 1.200E-01 4.000 0.000 I-C4H5 + C5H6 <=> C5H5 + C4H6 6.000E+12 0.000 0.000 C5H7 <=> H + C5H6 3.160E+15 0.000 150.630 C5H7 <=> L-C5H7 3.160E+15 0.000 165.280 L-C5H7 + H <=> L-C5H8 1.000E+14 0.000 0.000 C5H8 <=> H2 + C5H6 1.100E+13 0.000 246.000 L-C5H8 + H <=> L-C5H7 + H2 7.000E+06 2.000 20.920 L-C5H8 + H <=> C2H4 + AC3H5 3.350E+08 1.500 8.370 H + C6H (+M) <=> C6H2 (+M) 1.000E+23 -1.000 0.000 LOW / 3.750E+27 -4.800 7.950 / TROE / 0.6464 132. 1315. 5566. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H2 + C6H <=> H + C6H2 4.900E+05 2.500 2.340 H + C6H2 <=> C6H3 2.600E+46 -10.150 64.860 C6H2 + C2H <=> C6H + C2H2 2.000E+13 0.000 0.000 C6H2 + C2H <=> C4H2 + C4H 1.000E+13 0.000 0.000 H + C6H3 <=> C4H2 + C2H2 3.700E+22 -2.500 21.510 H + C6H3 <=> L-C6H4 5.300E+46 -10.680 38.790 H + C6H3 <=> H2 + C6H2 3.000E+13 0.000 0.000 L-C6H4 + H <=> N-C6H5 2.600E+43 -9.530 75.730 L-C6H4 + H <=> C6H5 4.700E+78 -20.100 123.430 L-C6H4 + H <=> H + C-C6H4 9.700E+48 -10.370 112.970 L-C6H4 + H <=> H2 + C6H3 6.650E+06 2.530 38.660 L-C6H4 + C2H <=> C6H3 + C2H2 2.000E+13 0.000 0.000 H + C-C6H4 <=> C6H5 1.000E+71 -16.880 143.100 C-C6H4 + C-C6H4 <=> BIPHEN 4.600E+12 0.000 0.000 N-C6H5 <=> C6H5 1.300E+59 -14.780 148.960 N-C6H5 <=> H + C-C6H4 1.500E+64 -15.320 257.330 N-C6H5 + H <=> I-C6H5 + H 9.200E+11 0.630 12.510 N-C6H5 + H <=> C4H4 + C2H2 1.300E+20 -1.850 12.390 N-C6H5 + H <=> L-C6H6 1.100E+42 -9.650 29.270 N-C6H5 + H <=> L-C6H4 + H2 1.500E+13 0.000 0.000 I-C6H5 + H <=> C4H4 + C2H2 3.700E+22 -2.500 21.510 I-C6H5 + H <=> L-C6H6 5.300E+46 -10.680 38.790 I-C6H5 + H <=> L-C6H4 + H2 3.000E+13 0.000 0.000 H + C6H5 (+M) <=> C6H6 (+M) 1.000E+20 0.000 0.000 LOW / 6.600E+69 -16.300 29.290 / TROE / 1. 0.1 584.9 6113. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + C6H5 <=> H2 + C-C6H4 4.400E-13 7.831 38.750 CH3 + C6H5 <=> C7H8 1.070E+65 -15.640 95.060 CH3 + C6H5 <=> H + C7H7 4.440E+33 -5.450 101.630 C6H5 + C2H2 <=> N-A1C2H2 9.900E+41 -9.260 65.690 C6H5 + C2H2 <=> H + A1C2H 8.320E+22 -2.680 72.810 C6H5 + C2H2 <=> A1C2H3* 7.900E+51 -12.410 74.350 C6H5 + C2H <=> A1C2H 2.540E+17 -1.489 6.450 C6H5 + C2H3 <=> A1C2H3 3.900E+38 -7.630 53.980 C6H5 + C2H3 <=> I-A1C2H2 + H 5.800E+18 -1.000 112.140 C6H5 + C2H3 <=> N-A1C2H2 + H 5.100E+20 -1.560 131.380 C6H5 + C2H4 <=> H + A1C2H3 5.000E+12 0.000 25.940 C6H5 + C3H3 <=> C9H8 1.510E+75 -17.845 165.690 C6H5 + C3H3 <=> H + C9H7 1.840E+72 -16.129 241.140 C6H5 + AC3H4 <=> H + C9H8 9.900E+30 -5.070 88.290 N-C4H3 + C6H5 <=> A2 1.510E+75 -17.845 165.690 N-C4H3 + C6H5 <=> H + A2-2 1.840E+72 -16.129 241.140 C6H5 + C4H4 <=> H + A2 9.900E+30 -5.070 88.290 C6H5 + C4H4 <=> C2H3 + A1C2H 3.200E+11 0.000 5.650 C6H5 + C4H4 <=> C2H + A1C2H3 3.200E+11 0.000 7.950 C6H5 + C4H6 <=> C2H3 + A1C2H3 3.200E+11 0.000 7.950 C6H5 + C5H6 <=> C6H6 + C5H5 1.000E-01 4.000 0.000 C6H5 + C6H5 <=> P2 5.940E+42 -8.830 57.870 C6H5 + C6H5 <=> P2- + H 8.600E+13 0.500 145.690 L-C6H6 + H <=> N-C6H7 1.500E+16 -1.690 6.690 L-C6H6 + H <=> C-C6H7 4.700E+27 -6.110 15.900 L-C6H6 + H <=> H + C6H6 8.700E+16 -1.340 14.640 L-C6H6 + H <=> N-C6H5 + H2 6.650E+05 2.530 51.210 L-C6H6 + H <=> I-C6H5 + H2 3.330E+05 2.530 38.660 H + C6H6 <=> C-C6H7 4.800E+30 -6.540 -3.770 H + C6H6 <=> H2 + C6H5 3.030E+02 3.300 23.810 C6H6 + 1CH2 <=> C7H8 1.200E+14 0.000 0.000 C6H6 + 3CH2 <=> C7H8 5.000E+13 0.000 37.500 CH3 + C6H6 <=> CH4 + C6H5 2.000E+12 0.000 62.700 C6H6 + C2H <=> H + A1C2H 5.000E+13 0.000 0.000 C6H6 + C2H3 <=> H + A1C2H3 1.600E+12 0.000 26.780 C6H6 + C6H5 <=> P2 + H 1.900E+76 -18.900 165.150 N-C6H7 <=> C-C6H7 3.600E+27 -7.540 24.270 N-C6H7 <=> H + C6H6 8.800E+24 -4.860 56.070 N-C6H7 + H <=> I-C6H7 + H 1.600E+42 -8.180 91.220 N-C6H7 + H <=> C6H8 6.700E+65 -15.640 97.070 N-C6H7 + H <=> L-C6H6 + H2 1.500E+13 0.000 0.000 I-C6H7 + H <=> C6H8 1.400E+55 -12.320 80.760 I-C6H7 + H <=> L-C6H6 + H2 3.000E+13 0.000 0.000 H + C-C6H7 <=> H2 + C6H6 1.000E+13 0.000 0.000 H + C-C6H7 <=> C6H813 6.000E+13 0.000 0.000 H + C-C6H7 <=> C6H814 6.000E+13 0.000 0.000 C6H5 + C-C6H7 <=> C6H6 + C6H6 1.000E+12 0.000 0.000 C-C6H7 + C-C6H7 <=> C6H813 + C6H6 1.940E+15 -1.000 0.000 C-C6H7 + C-C6H7 <=> C6H814 + C6H6 1.670E+15 -1.000 0.000 H + C6H814 <=> H2 + C-C6H7 2.800E+13 0.000 9.450 C6H813 <=> H2 + C6H6 4.700E+13 0.000 257.750 C6H814 <=> H2 + C6H6 1.050E+12 0.000 178.620 C-C6H12 <=> 1-C6H12 5.010E+16 0.000 369.000 1-C6H12 <=> N-C3H7 + AC3H5 7.940E+15 0.000 296.000 C7H7 <=> C5H5 + C2H2 6.000E+13 0.000 293.000 C7H7 + 1CH2 <=> H + A1C2H3 2.400E+14 0.000 0.000 C7H7 + 3CH2 <=> H + A1C2H3 7.000E+13 0.000 37.500 CH3 + C7H7 <=> A1C2H5 1.190E+13 0.000 0.920 C7H7 + C2H2 <=> H + C9H8 1.600E+11 0.000 29.290 C7H7 + C3H3 <=> C10H10 1.000E+10 0.000 0.000 C7H7 + C6H5 <=> BENZYLB 1.190E+13 0.000 0.920 C7H7 + C6H6 <=> H + BENZYLB 1.200E+12 0.000 66.700 H + C7H8 <=> CH3 + C6H6 1.200E+13 0.000 21.540 H + C7H7 <=> C7H8 2.590E+14 0.000 0.000 H + C7H8 <=> H2 + C7H7 1.200E+14 0.000 34.460 H + C7H8 => H2 + C6H4CH3 3.230E+07 2.095 66.290 CH3 + C7H8 <=> CH4 + C7H7 3.160E+11 0.000 39.750 C7H8 + C6H5 <=> C7H7 + C6H6 2.100E+12 0.000 18.410 C7H8 + C2H3 <=> C7H7 + C2H4 3.980E+12 0.000 33.470 CH3 + C6H4CH3 => ACH3CH3 1.070E+65 -15.640 95.060 H + A1C2H <=> N-A1C2H2 1.200E+51 -11.690 72.390 H + A1C2H <=> I-A1C2H2 1.200E+51 -11.690 72.390 H + A1C2H <=> H2 + A1C2H* 2.500E+14 0.000 66.950 H + A1C2H <=> H2 + A1C2H- 2.500E+14 0.000 66.950 CH3 + A1C2H <=> CH4 + A1C2H* 1.670E+12 0.000 63.000 C2H + A1C2H <=> H + A1C2H)2 5.000E+13 0.000 0.000 C6H5 + A1C2H <=> H + A3 4.775E+12 0.000 18.030 H + A1C2H- (+M) <=> A1C2H (+M) 1.000E+20 0.000 0.000 LOW / 6.600E+69 -16.300 29.290 / TROE / 1. 0.1 584.9 6113. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + A1C2H* (+M) <=> A1C2H (+M) 1.000E+20 0.000 0.000 LOW / 6.600E+69 -16.300 29.290 / TROE / 1. 0.1 584.9 6113. / H2 / 2. / CH4 / 2. / C2H6 / 3. / C2H2 + A1C2H* <=> A2-1 2.000E+72 -17.740 153.140 C2H2 + A1C2H* <=> H + A1C2H)2 4.800E+29 -4.590 108.790 C2H2 + A1C2H* <=> H + A2T1 5.200E+64 -14.540 218.420 C6H6 + A1C2H* <=> H + A3 9.550E+11 0.000 18.030 A1C2H* + A1C2H <=> H + A4 1.720E+13 0.000 16.680 N-A1C2H2 + H <=> H2 + A1C2H 1.210E+14 0.000 0.000 N-A1C2H2 + H <=> I-A1C2H2 + H 1.200E+25 -2.420 127.620 N-A1C2H2 + C2H2 <=> H + A2 2.100E+15 -1.070 20.080 I-A1C2H2 + H <=> H2 + A1C2H 3.000E+13 0.000 0.000 A1C2H3 <=> I-A1C2H2 + H 3.800E+37 -6.550 477.840 A1C2H3 <=> N-A1C2H2 + H 1.300E+44 -8.360 524.700 H + A1C2H3 <=> N-A1C2H2 + H2 6.650E+06 2.530 51.210 H + A1C2H3 <=> I-A1C2H2 + H2 3.330E+05 2.530 38.660 H + A1C2H3 <=> H2 + A1C2H3* 2.500E+14 0.000 66.950 CH3 + A1C2H3 <=> N-A1C2H2 + CH4 2.270E+05 2.000 38.490 CH3 + A1C2H3 <=> CH4 + A1C2H3* 2.000E+12 0.000 62.700 H + A1C2H3* (+M) <=> A1C2H3 (+M) 1.000E+20 0.000 0.000 LOW / 6.600E+69 -16.300 29.290 / TROE / 1. 0.1 584.9 6113. / H2 / 2. / CH4 / 2. / C2H6 / 3. / CH3 + A1C2H3* <=> H + H + C9H8 5.000E+13 0.000 0.000 C2H2 + A1C2H3* <=> H + A2 2.100E+15 -1.070 25.110 H + A1C2H5 <=> H2 + H + A1C2H3 8.000E+13 0.000 34.460 H + A1C2H5 <=> C6H6 + C2H5 1.200E+13 0.000 21.340 A1C2H5 <=> H2 + A1C2H3 5.010E+12 0.000 267.790 H + ACH3CH2 <=> ACH3CH3 7.460E+13 0.000 0.330 H + ACH3CH3 <=> H2 + ACH3CH2 3.980E+02 3.440 13.050 H + C9H7 <=> C9H8 2.000E+14 0.000 0.000 C9H7 + C5H5 <=> H + H + A3 5.000E+11 0.000 16.700 H + C9H8 <=> H2 + C9H7 2.190E+08 1.770 12.550 H + A1C2H)2 <=> A2-1 4.000E+75 -18.060 144.350 H + A1C2H)2 <=> H + A2T1 2.700E+76 -17.320 243.520 H + A2T1 <=> A2-1 5.900E+61 -15.420 152.720 C-C6H4 + A2T1 <=> A2C6H4-1 4.580E+41 -8.730 53.310 C-C6H4 + A2T1 <=> FLTHN 6.500E+39 -7.560 114.060 C-C6H4 + A2T1 <=> A3R5 5.120E+60 -13.070 204.940 C-C6H4 + A2T1 <=> A3LR5 7.850E+55 -11.980 183.230 C-C6H4 + A2T2 <=> A2C6H4-2 4.580E+41 -8.730 53.310 C-C6H4 + A2T2 <=> FLTHN 6.500E+39 -7.560 114.060 C-C6H4 + A2T2 <=> A3R5 5.120E+60 -13.070 204.940 C-C6H4 + A2T2 <=> A3LR5 7.850E+55 -11.980 183.230 H + A2 <=> H2 + A2-1 3.230E+07 2.095 66.290 H + A2 <=> H2 + A2-2 3.230E+07 2.095 66.290 H + A2 <=> C10H9 5.000E+14 0.000 20.920 CH3 + A2 <=> CH4 + A2-1 1.000E+13 0.000 63.010 CH3 + A2 <=> CH4 + A2-2 2.000E+12 0.000 63.010 C2H + A2 <=> H + A2C2H-1 5.000E+13 0.000 0.000 C2H + A2 <=> H + A2C2H-2 5.000E+13 0.000 0.000 C2H3 + A2 <=> H + A2C2H3-2 7.940E+11 0.000 26.770 C6H5 + A2 <=> H2 + H + FLTHN 8.510E+11 0.000 16.680 C6H5 + A2 <=> H + A2C6H5-2 2.220E+84 -20.790 196.200 C7H7 + A2 <=> H + BENZNAP 1.200E+12 0.000 66.700 A2 + A1C2H* <=> H + BAA3L 8.510E+13 0.000 16.680 A2 + A1C2H* <=> H + CRYSN 8.510E+13 0.000 16.680 A2-2 + A2 <=> H2 + H + BKFLTHN 4.000E+13 0.000 16.740 A2-1 + A2 <=> H2 + H + BKFLTHN 4.000E+13 0.000 16.740 H + A2-1 (+M) <=> A2 (+M) 1.000E+20 0.000 0.000 LOW / 3.800+121 -31.434 78.240 / TROE / 0.2 122.8 478.4 5411.9 / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + A2-1 <=> H + A2-2 6.500E+45 -7.900 232.220 H + A2-1 <=> H2 + A2T1 4.400E-13 7.831 38.750 CH3 + A2-1 <=> H + A2CH2-1 1.700E+36 -5.910 144.900 CH3 + A2-1 <=> A2CH3-1 3.050E+52 -11.800 73.890 C2H2 + A2-1 <=> H + A2R5 1.800E+33 -5.910 82.430 C2H2 + A2-1 <=> H + A2C2H-1 9.600E-09 6.440 36.070 C2H2 + A2-1 <=> HA2R5 7.740E+45 -10.850 56.360 C2H4 + A2-1 <=> H + A2R5H2 2.510E+12 0.000 25.940 N-C4H3 + A2-1 <=> A3 1.510E+75 -17.845 165.690 N-C4H3 + A2-1 <=> H + A3-2 1.840E+72 -16.129 241.140 C4H4 + A2-1 <=> H + A3 9.900E+30 -5.070 88.290 C5H6 + A2-1 <=> C5H5 + A2 1.000E-01 4.000 0.000 C6H5 + A2-1 <=> H + H + FLTHN 1.390E+13 0.000 0.460 C6H6 + A2-1 <=> H2 + H + FLTHN 8.510E+11 0.000 16.680 A2-1 + A2-1 <=> PERYLN + H + H 1.390E+13 0.000 0.460 A2-1 + A2 <=> PERYLN + H2 + H 1.702E+12 0.000 16.680 H + A2-2 (+M) <=> A2 (+M) 1.000E+20 0.000 0.000 LOW / 9.500+123 -32.132 78.660 / TROE / 0.87 492.7 117.9 5652. / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + A2-2 <=> H2 + A2T2 4.400E-13 7.831 38.750 CH3 + A2-2 <=> H + A2CH2-2 1.700E+36 -5.910 144.900 CH3 + A2-2 <=> A2CH3-2 3.050E+52 -11.800 73.890 C2H2 + A2-2 <=> H + A2C2H-2 1.010E+26 -3.440 84.650 C2H2 + A2-2 <=> A2C2H2-2 2.770E+46 -10.900 59.460 C2H4 + A2-2 <=> H + A2C2H3-2 2.510E+12 0.000 25.940 C4H2 + A2-2 <=> A3L-2 4.670E+06 1.787 13.650 N-C4H3 + A2-2 <=> A3L 1.510E+75 -17.845 165.690 N-C4H3 + A2-2 <=> H + A3L-2 1.840E+72 -16.129 241.140 C4H4 + A2-2 <=> H + A3 9.900E+30 -5.070 88.290 C4H4 + A2-2 <=> H + A3L 9.900E+31 -5.070 88.290 C5H6 + A2-2 <=> C5H5 + A2 1.000E-01 4.000 0.000 C6H5 + A2-2 <=> A2C6H5-2 4.850E+27 -4.320 29.040 C6H6 + A2-2 <=> H + A2C6H5-2 2.220E+83 -20.790 196.200 C7H7 + A2-2 <=> BENZNAP 1.190E+13 0.000 0.920 A2-2 + A1C2H <=> H + BAA3L 8.510E+11 0.000 16.680 A2-2 + A1C2H <=> H + CRYSN 8.510E+11 0.000 16.680 A2-2 + A2-1 <=> H + H + BKFLTHN 5.000E+12 0.000 0.000 H + C10H9 <=> C10H10 1.000E+14 0.000 0.000 H + C10H10 <=> H2 + C10H9 2.000E+05 2.500 10.460 H + A2CH2-1 <=> A2CH3-1 1.000E+14 0.000 0.000 H + A2CH3-1 <=> CH3 + A2 1.200E+13 0.000 21.540 H + A2CH3-1 <=> H2 + A2CH2-1 3.980E+02 3.440 13.050 H + A2CH2-2 <=> A2CH3-2 1.000E+14 0.000 0.000 H + A2CH3-2 <=> CH3 + A2 1.200E+13 0.000 21.540 CH3 + A2CH2-2 <=> A2C2H5 1.190E+13 0.000 0.920 H + A2CH3-2 <=> H2 + A2CH2-2 3.980E+02 3.440 13.050 H + A2C2H-1* (+M) <=> A2C2H-1 (+M) 1.000E+20 0.000 0.000 LOW / 9.500+123 -32.132 78.660 / TROE / 0.87 492.7 117.9 5652. / H2 / 2. / CH4 / 2. / C2H6 / 3. / C2H2 + A2C2H-1* <=> A3-4 2.000E+72 -17.740 153.140 C2H2 + A2C2H-1* <=> H + A2C2H)2 4.800E+29 -4.590 108.790 C6H6 + A2C2H-1* <=> H + CRYSN 8.510E+11 0.000 16.680 A2C2H-1* + A1C2H <=> H + BAPYR 8.510E+11 0.000 16.680 H + A2C2H-2* (+M) <=> A2C2H-2 (+M) 1.000E+20 0.000 0.000 LOW / 3.800+121 -31.434 78.240 / TROE / 0.2 122.8 478.4 5411.9 / H2 / 2. / CH4 / 2. / C2H6 / 3. / C2H2 + A2C2H-2* <=> A3-1 2.000E+72 -17.740 153.140 C2H2 + A2C2H-2* <=> H + A2C2H)2 4.800E+29 -4.590 108.790 H + A2C2H-1 <=> A2C2H2-1 3.300E+51 -11.720 79.080 H + A2C2H-1 <=> H2 + A2C2H-1* 2.500E+14 0.000 66.950 H + A2C2H-1 <=> H + A2R5 1.000E+40 -7.790 87.870 C2H + A2C2H-1 <=> H + A2C2H)2 5.000E+13 0.000 0.000 A2C2H-1 + A1C2H* <=> H + BAPYR 8.510E+11 0.000 16.680 H + A2C2H-2 <=> H2 + A2C2H-2* 2.500E+14 0.000 66.950 H + A2C2H-2 <=> H2 + A2C2H-23 3.230E+07 2.095 66.290 C2H + A2C2H-2 <=> H + A2C2H)2 5.000E+13 0.000 0.000 A2C2H2-1 <=> H + A2R5 2.200E+50 -11.800 167.790 H + A2C2H2-2 <=> H2 + A2C2H-2 1.210E+14 0.000 0.000 A2C2H2-2 <=> H + A2C2H-2 2.740E+22 -4.061 154.980 H + A2C2H2-2 <=> A2C2H3-2 4.800E+10 -0.740 -31.930 H + A2C2H3-2 <=> H2 + A2C2H2-2 2.000E+07 2.000 25.110 H + A2R5 <=> H2 + A2R5-1 3.230E+07 2.095 82.850 H + A2R5 <=> H2 + A2R5-3 3.230E+07 2.095 66.290 H + A2R5 <=> H2 + A2R5-4 3.230E+07 2.095 66.290 H + A2R5 <=> H2 + A2R5-5 3.230E+07 2.095 66.290 H + A2R5-1 <=> A2R5 1.240E+33 -5.680 37.280 C2H2 + A2R5-1 <=> H + A2R5E-1 1.120E+26 -3.420 87.320 H + A2R5-3 <=> A2R5 1.150E+32 -5.370 35.400 C2H2 + A2R5-3 <=> H + A2R5E-3 1.120E+26 -3.420 87.320 H + A2R5-4 <=> A2R5 1.150E+32 -5.370 35.400 C2H2 + A2R5-4 <=> H + A2R5E-4 1.120E+26 -3.420 87.320 H + A2R5-5 <=> A2R5 1.150E+32 -5.370 35.400 C2H2 + A2R5-5 <=> H + A2R5E-5 2.500E-09 6.630 37.030 BIPHENH <=> H + BIPHEN 1.300E+16 0.000 138.930 H + BIPHENH <=> H2 + BIPHEN 6.020E+12 0.000 0.000 BIPHENH <=> H + A2R5 1.000E+13 0.000 83.680 C2H2 + A2C2H-23 <=> A3L-1 4.670E+06 1.787 13.650 H + A2C2H5 <=> H2 + H + A2C2H3-2 8.000E+13 0.000 34.460 HA2R5 + H <=> H2 + A2R5 1.810E+12 0.000 0.000 HA2R5 + H <=> A2R5H2 1.000E+14 0.000 0.000 H + A2R5H2 <=> HA2R5 + H2 5.400E+02 3.500 21.800 A2R5H2 <=> H2 + A2R5 4.700E+13 0.000 257.750 P2 + H <=> P2- + H2 3.230E+07 2.095 66.290 P2- + H <=> P2 1.170E+33 -5.570 36.650 P2- + C2H2 <=> H + A3 4.600E+06 1.970 30.540 BENZYLB* <=> fluorene + H 4.000E+11 0.000 16.740 H + BENZYLB <=> H2 + BENZYLB* 3.230E+07 2.095 66.290 H + A2C2H)2 <=> A3-1 2.000E+75 -18.060 144.350 H + A2C2H)2 <=> A3-4 2.000E+75 -18.060 144.350 H + A3-1 (+M) <=> A3 (+M) 1.000E+20 0.000 0.000 LOW / 4.000+142 -37.505 86.190 / TROE / 1. 1. 144.9 5632.8 / H2 / 2. / CH4 / 2. / C2H6 / 3. / H + A3-1 <=> H + A3-4 9.300E+58 -11.450 297.500 C2H2 + A3-1 <=> H + A3R5 7.180E+23 -2.498 67.620 C2H2 + A3-1 <=> H + A3C2H-1 1.010E-10 7.060 38.530 C4H4 + A3-1 <=> H + CRYSN 9.900E+31 -5.070 88.290 C6H5 + A3-1 <=> H + H + BBFLTHN 5.000E+12 0.000 0.000 C6H6 + A3-1 <=> H2 + H + BBFLTHN 4.000E+11 0.000 16.740 H + A3-2 <=> A3 2.150E+19 -1.550 7.110 C2H2 + A3-2 <=> H + A3C2H-2 1.030E+26 -3.360 93.090 C4H4 + A3-2 <=> H + CRYSN 9.900E+31 -5.070 88.290 H + A3-4 (+M) <=> A3 (+M) 1.000E+20 0.000 0.000 LOW / 2.100+133 -34.803 76.990 / TROE / 1. 1. 171.4 4992.8 / H2 / 2. / CH4 / 2. / C2H6 / 3. / CH3 + A3-4 <=> A3CH3 1.070E+65 -15.640 95.060 CH3 + A3-4 <=> H + A3CH2 5.000E+13 0.000 0.000 C2H2 + A3-4 <=> A3C2H2-4 6.500E+53 -12.590 112.550 C2H2 + A3-4 <=> H + A3C2H-4 3.400E+12 0.340 82.430 C2H2 + A3-4 <=> H + A4 3.740E+08 1.787 13.650 C6H5 + A3-4 <=> H + H + BEPYR 1.390E+13 0.000 0.460 C6H6 + A3-4 <=> H2 + H + BEPYR 8.510E+11 0.000 16.680 H + A3-9 <=> A3 2.150E+19 -1.550 7.110 C6H5 + A3-9 <=> H + H + BBFLTHN 5.000E+12 0.000 0.000 C6H6 + A3-9 <=> H2 + H + BBFLTHN 4.000E+11 0.000 16.740 H + A3 <=> H2 + A3-1 1.615E+09 2.095 66.290 H + A3 <=> H2 + A3-2 3.230E+07 2.095 66.290 H + A3 <=> H2 + A3-4 1.615E+09 2.095 66.290 H + A3 <=> H2 + A3-9 3.230E+07 2.095 66.290 C2H + A3 <=> H + A3C2H-4 5.000E+13 0.000 0.000 C6H5 + A3 <=> H2 + H + BEPYR 8.510E+11 0.000 16.680 A3L <=> A3 1.600E+13 0.000 271.970 H + A3L <=> H2 + A3L-1 3.230E+07 2.095 66.290 H + A3L <=> H2 + A3L-2 3.230E+07 2.095 66.290 H + A3L <=> H2 + A3L-9 3.230E+07 2.095 66.290 H + A3L-1 <=> A3L 2.150E+19 -1.550 7.110 C2H2 + A3L-1 <=> H + A3LR5 3.590E+22 -2.498 67.620 C2H2 + A3L-1 <=> H + A3LE-1 1.010E-10 7.060 38.530 C4H4 + A3L-1 <=> H + BAA3L 9.900E+31 -5.070 88.290 H + A3L-2 <=> A3L 2.150E+19 -1.550 7.110 C2H2 + A3L-2 <=> H + A3LE-2 1.030E+26 -3.360 93.090 C4H4 + A3L-2 <=> H + BAA3L 9.900E+31 -5.070 88.290 H + A3L-9 <=> A3L 2.150E+19 -1.550 7.110 C2H2 + A3L-9 <=> H + A3LR5 1.870E+07 1.787 13.650 H + A2R5E-3 <=> H2 + A2R5E34 3.230E+07 2.095 66.290 H + A2R5E-4 <=> H2 + A2R5E45 3.230E+07 2.095 66.290 H + A2R5E-4 <=> H2 + A2R5E43 3.230E+07 2.095 66.290 H + A2R5E-5 <=> H2 + A2R5E54 3.230E+07 2.095 66.290 C2H2 + A2R5E45 <=> A3R5-7* 1.870E+07 1.787 13.650 C2H2 + A2R5E54 <=> A3R5-10* 1.870E+07 1.787 13.650 C2H2 + A2R5E34 <=> A3LR5* 1.870E+07 1.787 13.650 C2H2 + A2R5E43 <=> A3LR5* 1.870E+07 1.787 13.650 H + A2R5E-1 <=> H2 + A2R5E12 3.230E+07 2.095 66.290 C2H2 + A2R5E12 <=> FLTHN-7 1.870E+07 1.787 13.650 A3CH2 <=> H + A3CH2R 1.000E+13 0.000 50.210 H + A3CH2 <=> A3CH3 1.000E+14 0.000 0.000 H + A3CH3 <=> H2 + A3CH2 3.980E+02 3.440 13.050 H + A3CH3 <=> CH3 + A3 5.780E+13 0.000 33.850 H + A3C2H-4 <=> A3C2H2-4 1.400E+56 -13.210 87.870 H + A3C2H-4 <=> H + A4 4.200E+27 -4.250 45.610 A3C2H2-4 <=> H + A4 6.300E+59 -14.700 154.400 H + A3C2H-1 <=> H2 + A3C2H-1* 3.230E+07 2.095 66.290 H + A3C2H-2 <=> H2 + A3C2H-2* 3.230E+07 2.095 66.290 C2H2 + A3C2H-1* <=> CRYSN-4 1.870E+07 1.787 13.650 C2H2 + A3C2H-2* <=> CRYSN-1 5.600E+05 2.282 13.640 H + A3LE-1 <=> H2 + A3LE-1P 3.230E+07 2.095 66.290 H + A3LE-2 <=> H2 + A3LE-2S 3.230E+07 2.095 66.290 H + A3LE-2 <=> H2 + A3LE-2P 3.230E+07 2.095 66.290 C2H2 + A3LE-1P <=> BAA3L-1 1.870E+07 1.787 13.650 C2H2 + A3LE-2S <=> BAA3L-4 1.870E+07 1.787 13.650 C2H2 + A3LE-2P <=> A4L* 1.870E+07 1.787 13.650 H + A4-1 <=> A4 5.000E+13 0.000 0.000 C2H2 + A4-1 <=> H + A4C2H-1 1.190E-09 6.780 43.810 C2H2 + A4-1 <=> H + CPCDA4 3.800E+22 -2.475 70.630 C6H5 + A4-1 <=> INA4 + H + H 5.000E+12 0.000 0.000 C6H6 + A4-1 <=> INA4 + H2 + H 4.000E+11 0.000 16.740 H + A4-2 <=> A4 5.000E+13 0.000 0.000 C2H2 + A4-2 <=> H + A4C2H-2 1.260E+29 -4.170 102.350 H + A4-4 <=> A4 5.000E+13 0.000 0.000 C2H2 + A4-4 <=> H + A4C2H-4 1.190E-09 6.780 43.810 C2H2 + A4-4 <=> H + CPCDA4 3.800E+22 -2.475 70.630 H + FLTHN <=> H2 + FLTHN-1 3.230E+07 2.095 66.290 H + FLTHN <=> H2 + FLTHN-3 3.230E+07 2.095 66.290 H + FLTHN-1 <=> FLTHN 5.000E+13 0.000 0.000 FLTHN-1 + C2H2 <=> H + BGHIF 1.870E+07 1.787 13.650 H + FLTHN-3 <=> FLTHN 5.000E+13 0.000 0.000 FLTHN-3 + C2H2 <=> H + CPCDFL 3.800E+22 -2.475 70.630 H + FLTHN-7 <=> FLTHN 5.000E+13 0.000 0.000 FLTHN-7 + C2H2 <=> H + BGHIF 1.870E+07 1.787 13.650 H + A4 <=> H2 + A4-1 3.230E+07 2.095 66.290 H + A4 <=> H2 + A4-2 3.230E+09 2.095 66.290 H + A4 <=> H2 + A4-4 1.292E+09 2.095 66.290 A2C6H4-1 <=> FLTHN 8.510E+12 0.000 263.020 A2C6H4-2 <=> A3LR5 8.510E+12 0.000 263.020 A3R5 <=> FLTHN 8.510E+12 0.000 263.020 H + A3R5-7* <=> A3R5 5.000E+13 0.000 0.000 H + A3R5-10* <=> A3R5 5.000E+13 0.000 0.000 H + A3LR5* <=> A3LR5 5.000E+13 0.000 0.000 A3LR5 <=> A3R5 8.510E+12 0.000 263.020 A3LR5 <=> FLTHN 8.510E+12 0.000 263.020 BENZNAP* <=> H + C17H12 1.000E+13 0.000 50.210 H + BENZNAP <=> H2 + BENZNAP* 3.230E+07 2.095 66.290 C2H2 + A4C2H-1* <=> BAPYR* 1.870E+07 1.787 13.650 C2H2 + A4C2H-2* <=> BAPYR* 1.870E+07 1.787 13.650 C2H2 + A4C2H-4* <=> BEPYR* 1.870E+07 1.787 13.650 H + A4C2H-1 <=> H2 + A4C2H-1* 3.230E+07 2.095 66.290 H + A4C2H-2 <=> H2 + A4C2H-2* 3.230E+09 2.095 66.290 H + A4C2H-4 <=> H2 + A4C2H-4* 1.920E+09 2.095 66.290 H + A4L* <=> A4L 5.000E+13 0.000 0.000 H + BAA3L <=> H2 + BAA3L-1 3.230E+09 2.095 66.290 H + BAA3L <=> H2 + BAA3L-12 3.230E+09 2.095 66.290 H + BAA3L <=> H2 + BAA3L-4 3.230E+07 2.095 66.290 H + BAA3L-1 <=> BAA3L 5.000E+13 0.000 0.000 C2H2 + BAA3L-1 <=> H + BAPYR 1.870E+08 1.787 13.650 H + BAA3L-12 <=> BAA3L 5.000E+13 0.000 0.000 C2H2 + BAA3L-12 <=> H + BAPYR 1.870E+08 1.787 13.650 H + BAA3L-4 <=> BAA3L 5.000E+13 0.000 0.000 H + BGHIF <=> H2 + BGHIF- 3.230E+07 2.095 66.290 C2H2 + BGHIF- <=> H + CPBFL 3.800E+22 -2.475 70.630 C2H2 + BGHIF- <=> H + COR 1.870E+07 1.787 13.650 H + CPCDA4 <=> H2 + CPCDA4* 3.230E+07 2.095 66.290 CPCDA4* + C2H2 <=> H + DCPA4 3.800E+22 -2.475 70.630 CPCDA4* + C2H2 <=> H + COR 3.800E+22 -2.475 70.630 H + CPCDFL <=> H2 + CPCDFL* 3.230E+07 2.095 66.290 CPCDFL* + C2H2 <=> H + CPBFL 1.870E+07 1.787 13.650 H + CRYSN-1 <=> CRYSN 5.000E+13 0.000 0.000 H + CRYSN-4 <=> CRYSN 5.000E+13 0.000 0.000 CRYSN-4 + C2H2 <=> H + BAPYR 1.870E+08 1.787 13.650 H + CRYSN-5 <=> CRYSN 5.000E+13 0.000 0.000 CRYSN-5 + C2H2 <=> H + BAPYR 1.870E+08 1.787 13.650 H + CRYSN <=> H2 + CRYSN-1 3.230E+07 2.095 66.200 H + CRYSN <=> H2 + CRYSN-4 3.230E+09 2.095 66.200 H + CRYSN <=> H2 + CRYSN-5 3.230E+09 2.095 66.200 H + BBFLTHN <=> H2 + BBFLTHN* 3.230E+07 2.095 66.290 C2H2 + BBFLTHN* <=> INA4 + H 1.870E+07 1.787 13.650 H + BAPYR <=> H2 + BAPYR* 3.230E+07 2.095 66.290 H + BAPYR* <=> BAPYR 5.000E+13 0.000 0.000 C2H2 + BAPYR* <=> H + ANTHAN 1.870E+07 1.787 13.650 H + BEPYR <=> H2 + BEPYR* 3.230E+09 2.095 66.290 H + BEPYR* <=> BEPYR 5.000E+13 0.000 0.000 C2H2 + BEPYR* <=> H + BGHIPE 1.870E+09 1.787 13.650 PERYLN + H <=> PERYLN* + H2 3.230E+09 2.095 66.290 PERYLN* + C2H2 <=> H + BGHIPE 1.870E+09 1.787 13.650 H + CPBFL <=> H2 + CPBFL* 3.230E+07 2.095 66.290 CPBFL* + C2H2 <=> H + COR1 1.870E+07 1.787 13.650 H + COR <=> H2 + COR- 3.230E+07 2.095 66.200 COR- + C2H2 <=> H + COR1 3.800E+22 -2.475 70.630 H + BGHIPE <=> H2 + BGHIPE* 3.230E+09 2.095 66.290 C2H2 + BGHIPE* <=> H + CPBPER 3.800E+22 -2.475 70.630 C2H2 + BGHIPE* <=> H + CORONEN 1.870E+09 1.787 13.650 H + COR1 <=> H2 + COR1- 3.230E+07 2.095 66.200 COR1- + C2H2 <=> H + COR2 1.870E+07 1.787 13.650 H + COR2 <=> H2 + COR2- 3.230E+07 2.095 66.200 COR2- + C2H2 <=> H + COR3 1.870E+07 1.787 13.650 H + COR3 <=> H2 + COR3- 3.230E+07 2.095 66.200 COR3- + C2H2 <=> H + COR4 1.870E+07 1.787 13.650 H + COR4 <=> H2 + COR4- 3.230E+07 2.095 66.200 COR4- + C2H2 <=> HB + H 1.870E+07 1.787 13.650 END